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刘小明团队
  发表日期:2018-10-22  作者:
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团队名称绿色功能材料与应用团队

联系方式xiaoming.liu@mail.zjxu.edu.cn; xiaoming.liu@ncu.edu.cn 0573-83643937 / 15858311808

团队网页:/xliu.html

团队介绍

本科研团队的负责人是浙江省钱江高级人才特聘教授、夺宝斗地主安卓版下载院长刘小明博士,研究领域包括新能源催化体系、生物无机化学、过渡金属配位催化等。自2011年以来,承担国家自然科学基金5项(在研1项、结题4项)、浙江省自然科学基金4项(在研3项、结题1项);J. Mat. Chem. B., Chem. Eur. J., Dalton Trans., Electrochim. Acta, Int. J. Hydrogen Energy, New J. Chem. 等国际学术期刊上发表SCI论文50;获得授权专利4项;出席国内外学术会议近40次;科研团队依托南昌大学、浙江师范大学、辽宁石油化工大学、江西理工大学、桂林理工大学等学校招收硕士、博士研究生,共计培养硕、博士35名。经过全体成员的共同努力,团队在国内外产生了一定的学术影响,具备了一定的学术地位。详细内容请见科研团队主页http://www.hkdyj114.com/xliu/

主要研究领域

1. 新能源催化体系:主要围绕催化放氢的新体系和催化机理开展研究工作。

2. 生物无机化学:1)基于铁羰基化合物的一氧化碳释放剂研究(释放方法、释放动力学和释放机理)。一氧化碳是一种药物,特别是能够改善缺血再灌注损失,从而提高器官移植成活率和降低术后并发症。2)基于松香衍生物及其金属配合物的抗乳腺癌活性研究,主要包括松香衍生物改性、金属配合物及其细胞毒性和构效关系研究。

3. 过渡金属配位催化:铜铁等过渡金属催化体系催化空气氧化醇的研究。

社会服务领域:

本团队在做好教学工作、应用基础研究的同时,围绕高品质纺织油剂的研发和应用,与桐昆集团和桐乡市金羊皮革化工有限公司深入开展产学研合作、共同开展应用型人才培养。

代表性成果(论文、专利与获奖)

1.      Bingying Rong, Wei Zhong*, Erxing Gu, Li Long, Lijuan Song*, Xiaoming Liu*, Probing the electron transfer mechanism of the half-sandwich iron(II)-carbonyl complexes and their catalysis on proton reduction, Electrochim. Acta, 2018, 283, 27–35.

2.      Jun Ou, Weihua Zheng, Zhiyin Xiao, Yuping Yan, Xiujuan Jiang, Yong Dou, Ran Jiang and Xiaoming Liu*, Core-shell materials bearing iron (II) carbonyl units and their CO-release via upconversion process, J. Mat. Chem. B., 2017, 5, 8161–8168.

3.      Wei Zhong, Zhiyin Xiao, Guifen Qian, Xiaoming Liu*, The influence of a peripheral functional group of diiron hexacarbonyl complexes on their electrochemistry and electrocatalytic reduction of proton, Electrochim. Acta, 2017, 247, 779–786.

4.      Yongpo Yang, Chunxin Lu, Hailong Wang, Xiaoming Liu*, Amide bond cleavage initiated by coordination with transition metal ions and tuned by an auxiliary ligand, Dalton Trans., 2016, 45, 10289–10296.

5.      Xinglong Zhu, Wei Zhong, Xiaoming Liu*, Polymers functionalized with 1,2-benzenedithiolate-bridged model compound of [FeFe]-hydrogenase: synthesis, characterization and their catalytic activity, Int. J. Hydrogen Energy, 2016, 41, 14068–14078.

6.      Xiujuan Jiang, Limei Chen, Xiu Wang, Li Long, Zhiyin Xiao and Xiaoming Liu*, Photoinduced Carbon Monoxide Release from Half-Sandwich Iron(II) Carbonyl Complexes by Visible Irradiation: Kinetic Analysis and Mechanistic Investigation, Chem. Eur. J., 2015, 21, 13065-13072.

7.      Guifen Qian, Hailong Wang, Wei Zhong and Xiaoming Liu*, Electrochemical investigation into the electron transfer mechanism of a diiron hexacarbonyl complex bearing a bridging naphthalene moiety, Electrochim. Acta, 2015, 163, 190-195.

8.      Li Wu, Wei Zhong, Beibei Xu, Zhenhong Wei, Xiaoming Liu*, Synthesis and characterization of copper (II) complexes with multidentate ligands as catalysts for the direct hydroxylation of benzene to phenol, Dalton Trans., 2015, 44, 8013–8020.

9.      Xiujuan Jiang, Li Long, Hailong Wang, Limei Chen, Xiaoming Liu*, Diiron hexacarbonyl complexes as potential CO-RMs: their CO-releasing initiated by the substitution reaction with cysteamine and structural correlation to the bridging linkage, Dalton Trans., 2014, 43, 9968–9975.

10.  Li Long, Xiujuan Jiang, Xiu Wang, Zhiyin Xiao, Xiaoming Liu*, Water-soluble diiron hexacarbonyl complex as a CO-RM: controllable CO-releasing, releasing mechanism and biocompatibility, Dalton Trans., 2013, 42, 15663–15669.

11.  Li Long, Zhiyin Xiao, Giuseppe Zampella*, Zhenhong Wei, Luca De Gioia, Xiaoming Liu*, The reactions of pyridinyl thioesters with triirondodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations, Dalton Trans., 2012, 41, 9482–9492.

12.  刘小明;姜秀娟;陈丽梅;张佳瑶;龙莉,一种促进一氧化碳释放剂释放一氧化碳并防止形成沉淀的方法,专利号:ZL01510180597.7授权日期:20171226日。专利证书号:第2754331号。

13.  钟伟;王宏丹;刘小明3-巯丙基三乙氧基硅烷的合成方法,专利号:ZL201510359710.8授权日期:20171031日。专利证书号:第2675818号。

14.  钟伟;刘小明,一种制备邻苯二硫酚的方法,专利号:ZL201510212276.0。授权日期:20160824日,专利证书号:第2210018号。

15.  姜秀娟;刘小明;龙莉;肖志音;曾艳,一种水溶性铁羰基化合物及其制备方法和应用,专利号:ZL 201210175853.X。授权日期:20150114,专利证书号:第1565669号。


 



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